Regioselective Ring-Opening Metathesis-Cross Metathesis of Bridgehead-Substituted 7-Azanorbornene
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Universidad de La Rioja
info
ISSN: 1523-7060
Year of publication: 2007
Volume: 9
Issue: 7
Pages: 1235-1238
Type: Article
More publications in: Organic Letters
Metrics
JCR (Journal Impact Factor)
- Year 2007
- Journal Impact Factor: 4.802
- Journal Impact Factor without self cites: 4.246
- Article influence score: 1.392
- Best Quartile: Q1
- Area: CHEMISTRY, ORGANIC Quartile: Q1 Rank in area: 4/56 (Ranking edition: SCIE)
SCImago Journal Rank
- Year 2007
- SJR Journal Impact: 3.207
- Best Quartile: Q1
- Area: Biochemistry Quartile: Q1 Rank in area: 18/329
- Area: Organic Chemistry Quartile: Q1 Rank in area: 7/159
- Area: Physical and Theoretical Chemistry Quartile: Q1 Rank in area: 6/156
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Abstract
Figure presented In this paper we describe a highly regioselective ring-opening metathesis-cross metathesis (ROM-CM) process between methyl N-Boc-7-azabicyclo[2.2.1]hept-2-en-1-carboxylate, a bridgehead-substituted 7-azanorbornene system, and electron-poor olefins. The reaction opens the way to the synthesis of interesting α-amino diacids and pyrrolizinone derivatives that incorporate quaternary stereocenters. © 2007 American Chemical Society.