Regioselective Ring-Opening Metathesis-Cross Metathesis of Bridgehead-Substituted 7-Azanorbornene

  1. Carreras, J. 1
  2. Avenoza, A. 1
  3. Busto, J.H. 1
  4. Peregrina, J.M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Journal:
Organic Letters

ISSN: 1523-7060

Year of publication: 2007

Volume: 9

Issue: 7

Pages: 1235-1238

Type: Article

DOI: 10.1021/OL0631051 SCOPUS: 2-s2.0-34147121488 WoS: WOS:000245084300016 GOOGLE SCHOLAR

More publications in: Organic Letters

Metrics

Cited by

  • Scopus Cited by: 28 (12-01-2023)
  • Web of Science Cited by: 27 (31-12-2022)

JCR (Journal Impact Factor)

  • Year 2007
  • Journal Impact Factor: 4.802
  • Journal Impact Factor without self cites: 4.246
  • Article influence score: 1.392
  • Best Quartile: Q1
  • Area: CHEMISTRY, ORGANIC Quartile: Q1 Rank in area: 4/56 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2007
  • SJR Journal Impact: 3.207
  • Best Quartile: Q1
  • Area: Biochemistry Quartile: Q1 Rank in area: 18/329
  • Area: Organic Chemistry Quartile: Q1 Rank in area: 7/159
  • Area: Physical and Theoretical Chemistry Quartile: Q1 Rank in area: 6/156

Abstract

Figure presented In this paper we describe a highly regioselective ring-opening metathesis-cross metathesis (ROM-CM) process between methyl N-Boc-7-azabicyclo[2.2.1]hept-2-en-1-carboxylate, a bridgehead-substituted 7-azanorbornene system, and electron-poor olefins. The reaction opens the way to the synthesis of interesting α-amino diacids and pyrrolizinone derivatives that incorporate quaternary stereocenters. © 2007 American Chemical Society.