Ring-Rearrangement Metathesis of 1-Substituted 7-Azanorbornenes as an Entry to 1-Azaspiro[4.5]decane systems

  1. Carreras, J. 1
  2. Avenoza, A. 1
  3. Busto, J.H. 1
  4. Peregrina, J.M. 1
  1. 1 Universidad de La Rioja

    Universidad de La Rioja

    Logroño, España

    GRID grid.119021.a

Journal of Organic Chemistry

ISSN: 0022-3263

Year of publication: 2011

Volume: 76

Issue: 9

Pages: 3381-3391

Type: Article

Export: RIS
DOI: 10.1021/jo200321t SCOPUS: 2-s2.0-79955554628 WoS: 000289956900044 GOOGLE SCHOLAR


Cited by

  • Scopus Cited by: 17 (12-06-2021)

Journal Citation Reports

  • Year 2011
  • Journal Impact Factor: 4.45
  • Best Quartile: Q1
  • Area: CHEMISTRY, ORGANIC Quartile: Q1 Rank in area: 9/56 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2011
  • SJR Journal Impact: 2.265
  • Best Quartile: Q1
  • Area: Organic Chemistry Quartile: Q1 Rank in area: 13/182


  • Year 2011
  • CiteScore of the Journal : 7.7
  • Area: Organic Chemistry Percentile: 92
  • Area: Medicine (all) Percentile: 89


Several metathesis sequences have been carried out using 7-azanorbornenes as starting materials. The occurrence of several exocyclic olefin patterns in the bridgehead position of this system opens the way to gain interesting spirocyclic compounds, which were achieved using several ring-rearrangement metatheses (RRM). The metathesis products, thus obtained, may be useful for the synthesis of new peptidomimetics and related compounds. © 2011 American Chemical Society.