Ring-Rearrangement Metathesis of 1-Substituted 7-Azanorbornenes as an Entry to 1-Azaspiro[4.5]decane systems
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1
Universidad de La Rioja
info
ISSN: 0022-3263
Argitalpen urtea: 2011
Alea: 76
Zenbakia: 9
Orrialdeak: 3381-3391
Mota: Artikulua
Beste argitalpen batzuk: Journal of Organic Chemistry
Lotura duten proiektuak
Laburpena
Several metathesis sequences have been carried out using 7-azanorbornenes as starting materials. The occurrence of several exocyclic olefin patterns in the bridgehead position of this system opens the way to gain interesting spirocyclic compounds, which were achieved using several ring-rearrangement metatheses (RRM). The metathesis products, thus obtained, may be useful for the synthesis of new peptidomimetics and related compounds. © 2011 American Chemical Society.