Trihidrocarbyltin complexes of transition metal cyanides

  1. Uson, R. 1
  2. Fornies, J. 1
  3. Uson, M.A. 1
  4. Lalinde, E. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Año de publicación: 1980

Volumen: 185

Número: 3

Páginas: 359-366

Tipo: Artículo

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Otras publicaciones en: Journal of Organometallic Chemistry

Resumen

Cationic single-bridged trinuclear cyano complexes are obtained by treating trihydrocarbyltin perchlorate (SnR3O2ClO2) (R alkyl or aryl) with neutral transition metal monocyanides, whereas treatment with the corresponding neutral or anionic transition metal polycyanides gives neutral single-bridged polymeric cyano compounds. In every case the tin atoms are pentacoordinated with the three R groups in the equatorial and two CN groups (or, respectively one CN and one OClO3 group) in the axial position of a trigonal bipyramid. © 1980.