Trihidrocarbyltin complexes of transition metal cyanides
- Uson, R. 1
- Fornies, J. 1
- Uson, M.A. 1
- Lalinde, E. 1
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1
Universidad de Zaragoza
info
ISSN: 0022-328X
Datum der Publikation: 1980
Ausgabe: 185
Nummer: 3
Seiten: 359-366
Art: Artikel
Andere Publikationen in: Journal of Organometallic Chemistry
Zusammenfassung
Cationic single-bridged trinuclear cyano complexes are obtained by treating trihydrocarbyltin perchlorate (SnR3O2ClO2) (R alkyl or aryl) with neutral transition metal monocyanides, whereas treatment with the corresponding neutral or anionic transition metal polycyanides gives neutral single-bridged polymeric cyano compounds. In every case the tin atoms are pentacoordinated with the three R groups in the equatorial and two CN groups (or, respectively one CN and one OClO3 group) in the axial position of a trigonal bipyramid. © 1980.