Trihidrocarbyltin complexes of transition metal cyanides
- Uson, R. 1
- Fornies, J. 1
- Uson, M.A. 1
- Lalinde, E. 1
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1
Universidad de Zaragoza
info
ISSN: 0022-328X
Année de publication: 1980
Volumen: 185
Número: 3
Pages: 359-366
Type: Article
D'autres publications dans: Journal of Organometallic Chemistry
Résumé
Cationic single-bridged trinuclear cyano complexes are obtained by treating trihydrocarbyltin perchlorate (SnR3O2ClO2) (R alkyl or aryl) with neutral transition metal monocyanides, whereas treatment with the corresponding neutral or anionic transition metal polycyanides gives neutral single-bridged polymeric cyano compounds. In every case the tin atoms are pentacoordinated with the three R groups in the equatorial and two CN groups (or, respectively one CN and one OClO3 group) in the axial position of a trigonal bipyramid. © 1980.