Phase Transfer Catalysis and Homogeneous Reactions with Oxyalkyl Radicals from Organomercurials
- Barluenga, J.
- López-Prado, Joaquín .
- Campos, P.J.
- Asensio, G.
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1
Universidad de Oviedo
info
ISSN: 0040-4020
Año de publicación: 1983
Volumen: 39
Número: 17
Páginas: 2863-2868
Tipo: Artículo
Otras publicaciones en: Tetrahedron
Resumen
β-Alkoxy- and β-hydroxyalkyl radicals generated by sodium borohydride reduction of oxymercurials react with electron deficient olefins to give addition compounds in an homogeneous process. Heterogeneous reactions are also successful in the presence of catalytic amounts of surfactants and provide a superior method for the "one pot" reductive alkylation of oxymercurials. © 1983.