Phase Transfer Catalysis and Homogeneous Reactions with Oxyalkyl Radicals from Organomercurials

  1. Barluenga, J.
  2. López-Prado, Joaquín .
  3. Campos, P.J.
  4. Asensio, G.
  1. 1 Universidad de Oviedo
    info

    Universidad de Oviedo

    Oviedo, España

    ROR https://ror.org/006gksa02

Zeitschrift:
Tetrahedron

ISSN: 0040-4020

Datum der Publikation: 1983

Ausgabe: 39

Nummer: 17

Seiten: 2863-2868

Art: Artikel

SCOPUS: 2-s2.0-0001100882 GOOGLE SCHOLAR

Andere Publikationen in: Tetrahedron

Zusammenfassung

β-Alkoxy- and β-hydroxyalkyl radicals generated by sodium borohydride reduction of oxymercurials react with electron deficient olefins to give addition compounds in an homogeneous process. Heterogeneous reactions are also successful in the presence of catalytic amounts of surfactants and provide a superior method for the "one pot" reductive alkylation of oxymercurials. © 1983.