Phase Transfer Catalysis and Homogeneous Reactions with Oxyalkyl Radicals from Organomercurials
- Barluenga, J.
- López-Prado, Joaquín .
- Campos, P.J.
- Asensio, G.
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Universidad de Oviedo
info
ISSN: 0040-4020
Année de publication: 1983
Volumen: 39
Número: 17
Pages: 2863-2868
Type: Article
D'autres publications dans: Tetrahedron
Résumé
β-Alkoxy- and β-hydroxyalkyl radicals generated by sodium borohydride reduction of oxymercurials react with electron deficient olefins to give addition compounds in an homogeneous process. Heterogeneous reactions are also successful in the presence of catalytic amounts of surfactants and provide a superior method for the "one pot" reductive alkylation of oxymercurials. © 1983.