Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes
- Uson, R. 1
- Oro, L.A. 1
- Ciriano, M.A. 1
- Pinillos, M.T. 1
- Cabeza, J.A. 1
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1
Universidad de Zaragoza
info
ISSN: 0022-328X
Ano de publicación: 1981
Volume: 221
Número: 2
Páxinas: 249-255
Tipo: Artigo
Outras publicacións en: Journal of Organometallic Chemistry
Resumo
Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az imidazolate (Im) or pyrazolate (Pz) anions) as ligands. Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes [Y2Rh(μ-Pz)]2 and [Ph3PAu(μ-Pz)AuPPh32]ClO4, [Au(PPh3)2]ClO4 or AuClPPh3 as end-products. © 1981.