Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes
- Uson, R. 1
- Oro, L.A. 1
- Ciriano, M.A. 1
- Pinillos, M.T. 1
- Cabeza, J.A. 1
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1
Universidad de Zaragoza
info
ISSN: 0022-328X
Argitalpen urtea: 1981
Alea: 221
Zenbakia: 2
Orrialdeak: 249-255
Mota: Artikulua
Beste argitalpen batzuk: Journal of Organometallic Chemistry
Laburpena
Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az imidazolate (Im) or pyrazolate (Pz) anions) as ligands. Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes [Y2Rh(μ-Pz)]2 and [Ph3PAu(μ-Pz)AuPPh32]ClO4, [Au(PPh3)2]ClO4 or AuClPPh3 as end-products. © 1981.