Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes

  1. Uson, R. 1
  2. Oro, L.A. 1
  3. Ciriano, M.A. 1
  4. Pinillos, M.T. 1
  5. Cabeza, J.A. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revue:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Année de publication: 1981

Volumen: 221

Número: 2

Pages: 249-255

Type: Article

SCOPUS: 2-s2.0-0001002245 GOOGLE SCHOLAR

D'autres publications dans: Journal of Organometallic Chemistry

Résumé

Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az imidazolate (Im) or pyrazolate (Pz) anions) as ligands. Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes [Y2Rh(μ-Pz)]2 and [Ph3PAu(μ-Pz)AuPPh32]ClO4, [Au(PPh3)2]ClO4 or AuClPPh3 as end-products. © 1981.