Cis-Bis[diphenyl(phenylsulfanylmethyl)diphenylphosphine-hP]bis(pentafluorophenyl)gold(III) perchlorate chloroform solvate

  1. Jones, P.G. 3
  2. Fernández, E.J. 1
  3. López-De-Luzuriaga, J.M. 1
  4. Laguna, A. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Revue:
Acta Crystallographica Section E: Structure Reports Online

ISSN: 1600-5368

Année de publication: 2006

Volumen: 62

Número: 8

Pages: 1997-1999

Type: Article

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DOI: 10.1107/S1600536806028856 SCOPUS: 2-s2.0-33747180383 WoS: WOS:000239392200112 GOOGLE SCHOLAR

D'autres publications dans: Acta Crystallographica Section E: Structure Reports Online

Résumé

The title compound, [Au(C6F5)2(C 19H17PS)2]ClO4·CHCl 3, involves a planar AuIII centre with Au-P = 2.3818 (14) and 2.3990 (15) Å, and Au-C = 2.079 (5) and 2.083 (5) Å. Ligand S atoms are not involved in coordination at gold. The P-C-S-C torsion angles are very approximately antiperiplanar. The anion is well resolved and acts as an acceptor for C-H⋯O interactions. © 2006 International Union of Crystallography. All rights reserved.