Cis-Bis[diphenyl(phenylsulfanylmethyl)diphenylphosphine-hP]bis(pentafluorophenyl)gold(III) perchlorate chloroform solvate
- Jones, P.G. 3
- Fernández, E.J. 1
- López-De-Luzuriaga, J.M. 1
- Laguna, A. 2
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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3
Braunschweig University of Technology
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ISSN: 1600-5368
Datum der Publikation: 2006
Ausgabe: 62
Nummer: 8
Seiten: 1997-1999
Art: Artikel
beta Ver similares en nube de resultadosAndere Publikationen in: Acta Crystallographica Section E: Structure Reports Online
Zusammenfassung
The title compound, [Au(C6F5)2(C 19H17PS)2]ClO4·CHCl 3, involves a planar AuIII centre with Au-P = 2.3818 (14) and 2.3990 (15) Å, and Au-C = 2.079 (5) and 2.083 (5) Å. Ligand S atoms are not involved in coordination at gold. The P-C-S-C torsion angles are very approximately antiperiplanar. The anion is well resolved and acts as an acceptor for C-H⋯O interactions. © 2006 International Union of Crystallography. All rights reserved.