[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence
- Fernández, E.J. 1
- Laguna, A. 2
- López-de-Luzuriaga, J.M. 1
- Olmos, M.E. 1
- Pérez, J. 1
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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ISSN: 1359-7345
Año de publicación: 2003
Volumen: 9
Número: 14
Páginas: 1760-1761
Tipo: Artículo
beta Ver similares en nube de resultadosOtras publicaciones en: Chemical Communications
Resumen
The complex [{AuTl(C6Cl5)2(toluene)} 2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au-Tl interaction ever found, a toluene molecule in a η6-mode and the "disappearance" of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.