[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. López-de-Luzuriaga, J.M. 1
  4. Olmos, M.E. 1
  5. Pérez, J. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Revue:
Chemical Communications

ISSN: 1359-7345

Année de publication: 2003

Volumen: 9

Número: 14

Pages: 1760-1761

Type: Article

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SCOPUS: 2-s2.0-0037963646 WoS: WOS:000183872700071 GOOGLE SCHOLAR lock_openAccès ouvert editor

D'autres publications dans: Chemical Communications

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Résumé

The complex [{AuTl(C6Cl5)2(toluene)} 2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au-Tl interaction ever found, a toluene molecule in a η6-mode and the "disappearance" of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.