[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. López-de-Luzuriaga, J.M. 1
  4. Olmos, M.E. 1
  5. Pérez, J. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Revista:
Chemical Communications

ISSN: 1359-7345

Any de publicació: 2003

Volum: 9

Número: 14

Pàgines: 1760-1761

Tipus: Article

SCOPUS: 2-s2.0-0037963646 WoS: WOS:000183872700071 GOOGLE SCHOLAR lock_openAccés obert editor

Altres publicacions en: Chemical Communications

Repositori institucional: lock_openAccés obert Editor

Resum

The complex [{AuTl(C6Cl5)2(toluene)} 2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au-Tl interaction ever found, a toluene molecule in a η6-mode and the "disappearance" of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.