[Au(C6F5)3(PPh2H)]: A Precursor for the Synthesis of Gold(III) Phosphide Complexes
- Blanco, M.C. 1
- Fernández, E.J. 1
- Jones, P.G. 3
- Laguna, A. 2
- López-de-Luzuriaga, J.M. 1
- Olmos, M.E. 1
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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3
Braunschweig University of Technology
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ISSN: 1433-7851
Año de publicación: 1998
Volumen: 37
Número: 21
Páginas: 3042-3043
Tipo: Artículo
beta Ver similares en nube de resultadosOtras publicaciones en: Angewandte Chemie International
Resumen
The covalent radius of Au(I) is about 0.07 Å smaller than that of Ag(I). This was determined from the crystal structures of the isostructural complexes [N(PPh3][{Au(C6F5)3-(μ-PPh2)}2M] (M = Au (structure shown in the picture), Ag). These mixed Au(III)-M phosphides were synthesized from [Au(C6F5)3-(PPh2H)], the first gold complex to contain a secondary phosphane.