[Au(C6F5)3(PPh2H)]: A Precursor for the Synthesis of Gold(III) Phosphide Complexes

  1. Blanco, M.C. 1
  2. Fernández, E.J. 1
  3. Jones, P.G. 3
  4. Laguna, A. 2
  5. López-de-Luzuriaga, J.M. 1
  6. Olmos, M.E. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Revista:
Angewandte Chemie International

ISSN: 1433-7851

Any de publicació: 1998

Volum: 37

Número: 21

Pàgines: 3042-3043

Tipus: Article

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DOI: 10.1002/(SICI)1521-3773(19981116)37:21<3042::AID-ANIE3042>3.0.CO;2-C SCOPUS: 2-s2.0-0345698753 WoS: WOS:000077114900024 GOOGLE SCHOLAR

Altres publicacions en: Angewandte Chemie International

Repositori institucional: lock_openAccés obert Editor

Resum

The covalent radius of Au(I) is about 0.07 Å smaller than that of Ag(I). This was determined from the crystal structures of the isostructural complexes [N(PPh3][{Au(C6F5)3-(μ-PPh2)}2M] (M = Au (structure shown in the picture), Ag). These mixed Au(III)-M phosphides were synthesized from [Au(C6F5)3-(PPh2H)], the first gold complex to contain a secondary phosphane.