Tris(pentafluorophenyl)[2-(diphenylphosphino)- thiophenol-kappa P]gold(III) dichloromethane solvate

Jones, Peter G.; Terroba, Raquel; Fernández Garbayo, Eduardo Jacinto; Laguna, Mariano

doi:10.1107/S1600536802002404

Tris(pentafluorophenyl)[2-(diphenylphosphino)- thiophenol-kappa P]gold(III) dichloromethane solvate

Jones, Peter G.
Terroba, Raquel
Fernández Garbayo, Eduardo Jacinto
Laguna, Mariano

Revista:

Acta Crystallographica Section E: Structure Reports Online

ISSN: 1600-5368

Ano de publicación: 2002

Volume: 58

Número: 3

Páxinas: 90-92

Tipo: Artigo

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DOI: 10.1107/S1600536802002404 WoS: WOS:000174090000010 GOOGLE SCHOLAR Acceso aberto editor

Outras publicacións en: Acta Crystallographica Section E: Structure Reports Online

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Resumo

The title compound, [Au(C6F5)3(PPh2C6H4SH)]·CH2Cl2, presents a square-planar geometry. The long Au-P bond, 2.3884 (16) Å, is consistent with an appreciable trans influence of the pentafluorophenyl group. The intramolecular Au...S contact is 3.594 (2) Å.