Tris(pentafluorophenyl)[2-(diphenylphosphino)- thiophenol-kappa P]gold(III) dichloromethane solvate

  1. Jones, Peter G.
  2. Terroba, Raquel
  3. Fernández Garbayo, Eduardo Jacinto
  4. Laguna, Mariano
Journal:
Acta Crystallographica Section E: Structure Reports Online

ISSN: 1600-5368

Year of publication: 2002

Volume: 58

Issue: 3

Pages: 90-92

Type: Article

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DOI: 10.1107/S1600536802002404 WoS: WOS:000174090000010 GOOGLE SCHOLAR lock_openOpen access editor

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Abstract

The title compound, [Au(C6F5)3(PPh2C6H4SH)]·CH2Cl2, presents a square-planar geometry. The long Au-P bond, 2.3884 (16) Å, is consistent with an appreciable trans influence of the pentafluorophenyl group. The intramolecular Au...S contact is 3.594 (2) Å.