Photochemically driven addition of iminyl radicals to alkynyl Fisher carbene complexes

  1. Blanco-Lomas, M. 1
  2. Caballero, A. 1
  3. Campos, P.J. 1
  4. González, H.F. 1
  5. López-Sola, S. 1
  6. Rivado-Casas, L. 1
  7. Rodríguez, M.A. 1
  8. Sampedro, D. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Journal:
Organometallics

ISSN: 0276-7333

Year of publication: 2011

Volume: 30

Issue: 13

Pages: 3677-3682

Type: Article

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DOI: 10.1021/OM200438Y SCOPUS: 2-s2.0-79959947598 WoS: WOS:000292417900033 GOOGLE SCHOLAR

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Abstract

Nitrogen-centered radicals, generated by the action of UV light, are capable of reacting with alkynyl Fischer carbene complexes in two ways, 1,2- and 1,4-addition. Our results constitute the first reported example of a photochemically driven reaction of this kind. © 2011 American Chemical Society.