Photochemically driven addition of iminyl radicals to alkynyl Fisher carbene complexes
- Blanco-Lomas, M. 1
- Caballero, A. 1
- Campos, P.J. 1
- González, H.F. 1
- López-Sola, S. 1
- Rivado-Casas, L. 1
- Rodríguez, M.A. 1
- Sampedro, D. 1
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1
Universidad de La Rioja
info
ISSN: 0276-7333
Datum der Publikation: 2011
Ausgabe: 30
Nummer: 13
Seiten: 3677-3682
Art: Artikel
Andere Publikationen in: Organometallics
Projekte im Zusammenhang
Zusammenfassung
Nitrogen-centered radicals, generated by the action of UV light, are capable of reacting with alkynyl Fischer carbene complexes in two ways, 1,2- and 1,4-addition. Our results constitute the first reported example of a photochemically driven reaction of this kind. © 2011 American Chemical Society.