Synthesis of gold(III) complexes of 2-(diphenylthiophosphino)aniline

  1. Fernández, E.J. 1
  2. García-Luzuriaga, E. 1
  3. Laguna, A. 2
  4. López-de-Luzuriaga, J.M. 1
  5. Elena Olmos, M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Journal:
Gold Bulletin

ISSN: 0017-1557

Year of publication: 2010

Volume: 43

Issue: 2

Pages: 80-87

Type: Article

More publications in: Gold Bulletin

Metrics

Cited by

  • Scopus Cited by: 2 (12-01-2023)
  • Web of Science Cited by: 2 (06-02-2023)

JCR (Journal Impact Factor)

  • Year 2010
  • Journal Impact Factor: 2.719
  • Journal Impact Factor without self cites: 2.359
  • Article influence score: 0.728
  • Best Quartile: Q1
  • Area: MATERIALS SCIENCE, MULTIDISCIPLINARY Quartile: Q1 Rank in area: 42/225 (Ranking edition: SCIE)
  • Area: CHEMISTRY, PHYSICAL Quartile: Q2 Rank in area: 49/127 (Ranking edition: SCIE)
  • Area: CHEMISTRY, INORGANIC & NUCLEAR Quartile: Q2 Rank in area: 12/43 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2010
  • SJR Journal Impact: 1.231
  • Best Quartile: Q1
  • Area: Inorganic Chemistry Quartile: Q1 Rank in area: 13/67
  • Area: Materials Science (miscellaneous) Quartile: Q1 Rank in area: 70/627

Abstract

The gold(III) complex [Au(C 6F 5) 2(SPNH 2)]ClO 4 (1) containing the S,N-donor ligand 2-(diphenylthiop hosphino)aniline (S=PNH 2) can be easily prepared by treatment of S=PNH 2 with [Au(C 6F 5) 2(OEt 2) 2]ClO 4 and deprotonated with PPN(acac) to afford [Au(C 6F 5) 2(SPNH)] (2). Complex 2 can also be obtained in a one-step reaction from SPNH 2 and [Au(C 6F 5) 2(acac)]. The electronic density in excess in 2 can be employed to incorporate a new metallic fragment to give the mixed complexes [Au(C 6F 5) 2{SPNH(MPPh 3)}]ClO 4 (M = Au (3), Ag (4)). The crystal structures of 1 and 2 have been determined by X-ray diffraction, showing that the electronic density in excess in complex 2 is located in the Au-N-C fragment.