Synthesis of gold(III) complexes of 2-(diphenylthiophosphino)aniline

  1. Fernández, E.J. 1
  2. García-Luzuriaga, E. 1
  3. Laguna, A. 2
  4. López-de-Luzuriaga, J.M. 1
  5. Elena Olmos, M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Aldizkaria:
Gold Bulletin

ISSN: 0017-1557

Argitalpen urtea: 2010

Alea: 43

Zenbakia: 2

Orrialdeak: 80-87

Mota: Artikulua

DOI: 10.1007/BF03214972 SCOPUS: 2-s2.0-77956214942 WoS: WOS:000280335400001 GOOGLE SCHOLAR

Beste argitalpen batzuk: Gold Bulletin

Lotura duten proiektuak

Diseño de compuestos homo y heterometálicos del grupo 11. Consecuencias estructurales, ópticas, biológicas y posibles aplicaciones.

2007/00078/001

Laburpena

The gold(III) complex [Au(C 6F 5) 2(SPNH 2)]ClO 4 (1) containing the S,N-donor ligand 2-(diphenylthiop hosphino)aniline (S=PNH 2) can be easily prepared by treatment of S=PNH 2 with [Au(C 6F 5) 2(OEt 2) 2]ClO 4 and deprotonated with PPN(acac) to afford [Au(C 6F 5) 2(SPNH)] (2). Complex 2 can also be obtained in a one-step reaction from SPNH 2 and [Au(C 6F 5) 2(acac)]. The electronic density in excess in 2 can be employed to incorporate a new metallic fragment to give the mixed complexes [Au(C 6F 5) 2{SPNH(MPPh 3)}]ClO 4 (M = Au (3), Ag (4)). The crystal structures of 1 and 2 have been determined by X-ray diffraction, showing that the electronic density in excess in complex 2 is located in the Au-N-C fragment.