Photochemistry of acyloximes: synthesis of heterocycles and natural products
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Universidad de La Rioja
info
ISSN: 0040-4020
Datum der Publikation: 2010
Ausgabe: 66
Nummer: 46
Seiten: 8828-8831
Art: Artikel
Andere Publikationen in: Tetrahedron
Projekte im Zusammenhang
Zusammenfassung
New applications of the photochemically generated iminyl radicals ring closure onto phenyl, thiophenyl, and pyridinyl rings are presented. The influence on the reactivity of different substituent throughout the acyloxime structure is discussed. Some observed effects are interpreted from computational studies. This reaction provides a new, simple, and straightforward method for the preparation of several polycyclic heteroaromatic compounds and it has been applied to the synthesis of some natural products. © 2010 Elsevier Ltd. All rights reserved.