Photochemistry of acyloximes: synthesis of heterocycles and natural products

  1. Alonso, R. 1
  2. Caballero, A. 1
  3. Campos, P.J. 1
  4. Rodríguez, M.A. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Tetrahedron

ISSN: 0040-4020

Any de publicació: 2010

Volum: 66

Número: 46

Pàgines: 8828-8831

Tipus: Article

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DOI: 10.1016/J.TET.2010.09.078 SCOPUS: 2-s2.0-77958195697 WoS: WOS:000284499100004 GOOGLE SCHOLAR

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Resum

New applications of the photochemically generated iminyl radicals ring closure onto phenyl, thiophenyl, and pyridinyl rings are presented. The influence on the reactivity of different substituent throughout the acyloxime structure is discussed. Some observed effects are interpreted from computational studies. This reaction provides a new, simple, and straightforward method for the preparation of several polycyclic heteroaromatic compounds and it has been applied to the synthesis of some natural products. © 2010 Elsevier Ltd. All rights reserved.