A Luminescent Pt3Pb cluster with three Pt(II)®Pb(II) bonds
- Ara, I. 1
- Falvello, L.R. 1
- Forniés, J. 1
- Gomez-Cordón, J. 2
- Lalinde, E. 2
- Merino, R.I. 1
- Usón, I. 1
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1
Universidad de Zaragoza
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2
Universidad de La Rioja
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ISSN: 0022-328X
Año de publicación: 2002
Volumen: 663
Número: 1-2
Páginas: 284-288
Tipo: Artículo
beta Ver similares en nube de resultadosOtras publicaciones en: Journal of Organometallic Chemistry
Resumen
The reaction between the pentafluorophenylplatinate derivative Pb(ClO4)2 (1.5:1) in dry tetrahydrofuran yields the tetranuclear complex (NBu4)[Pb{Pt(μ-Cl) (C6F5)2}3] (1). The crystal structure of this compound has been analyzed by X-ray diffraction and reveals the presence of three Pt→Pb metal-metal bonds. This complex shows luminescence at low temperature. © 2002 Elsevier Science B.V. All rights reserved.