A Luminescent Pt3Pb cluster with three Pt(II)®Pb(II) bonds

  1. Ara, I. 1
  2. Falvello, L.R. 1
  3. Forniés, J. 1
  4. Gomez-Cordón, J. 2
  5. Lalinde, E. 2
  6. Merino, R.I. 1
  7. Usón, I. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revue:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Année de publication: 2002

Volumen: 663

Número: 1-2

Pages: 284-288

Type: Article

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DOI: 10.1016/S0022-328X(02)01991-5 SCOPUS: 2-s2.0-0037011738 WoS: WOS:000179775800037 GOOGLE SCHOLAR

D'autres publications dans: Journal of Organometallic Chemistry

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Résumé

The reaction between the pentafluorophenylplatinate derivative Pb(ClO4)2 (1.5:1) in dry tetrahydrofuran yields the tetranuclear complex (NBu4)[Pb{Pt(μ-Cl) (C6F5)2}3] (1). The crystal structure of this compound has been analyzed by X-ray diffraction and reveals the presence of three Pt→Pb metal-metal bonds. This complex shows luminescence at low temperature. © 2002 Elsevier Science B.V. All rights reserved.