Synthesis and structure of neutral and cationic pentahaloaryl palladium(II) isonitrile complexes
- Usón, R. 1
- Forniés, J. 1
- Espinet, P. 1
- Lalinde, E. 1
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1
Universidad de Zaragoza
info
ISSN: 0022-328X
Year of publication: 1981
Volume: 220
Issue: 3
Pages: 393-399
Type: Article
More publications in: Journal of Organometallic Chemistry
Abstract
Complexes of the types (a) trans- and cis-[Pd(C6X5)2 (CNR)2], (b) trans- [Pd(C6X5)Cl(CNR)2] and (c) [Pd(C6X5)(CNR)3]ClO4 (X = F or Cl;R = But cyclohexyl or p-tolyl) have been made by replacement of the tetrahydrothiophen or Cl groups of appropriate precursors by isonitrile. Their structures have been assigned on the basis of their IR and 1H NMR spectra. © 1981.