Synthesis and structure of neutral and cationic pentahaloaryl palladium(II) isonitrile complexes

  1. Usón, R. 1
  2. Forniés, J. 1
  3. Espinet, P. 1
  4. Lalinde, E. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Any de publicació: 1981

Volum: 220

Número: 3

Pàgines: 393-399

Tipus: Article

DOI: 10.1016/S0022-328X(00)82291-3 SCOPUS: 2-s2.0-49049151687 GOOGLE SCHOLAR

Altres publicacions en: Journal of Organometallic Chemistry

Resum

Complexes of the types (a) trans- and cis-[Pd(C6X5)2 (CNR)2], (b) trans- [Pd(C6X5)Cl(CNR)2] and (c) [Pd(C6X5)(CNR)3]ClO4 (X = F or Cl;R = But cyclohexyl or p-tolyl) have been made by replacement of the tetrahydrothiophen or Cl groups of appropriate precursors by isonitrile. Their structures have been assigned on the basis of their IR and 1H NMR spectra. © 1981.