Ab Initio calculations for N-methyl-1-(N'-acetylamino)-t-2-phenylcyclohexane-r-1-carboxamide: a gamma-turn mimetic
- Avenoza, A. 1
- Campos, P.J. 1
- Cativiela, C. 2
- Peregrina, J.M. 1
- Rodríguez, M.A. 1
-
1
Universidad de La Rioja
info
-
2
Instituto de Nanociencia y Materiales de Aragón
info
ISSN: 0040-4020
Año de publicación: 1999
Volumen: 55
Número: 5
Páginas: 1399-1406
Tipo: Artículo
beta Ver similares en nube de resultadosOtras publicaciones en: Tetrahedron
Resumen
An ab initio quantum mechanical study of the conformational preferences of N-methyl-1-(N'-acetylamino)-t-2-phenylcyclohexane-r-1-carboxamide, a cyclic analogue of phenylalanine (MeNH-c6Phe-CONHMe), has been performed at the HF/3-21G and HF/6-31G computational levels. Results show a γ-turn geometry. Furthermore, this report describes the synthesis of the above peptide analogue in its racemic form.