A General and Useful Copper(Ii)-promoted Iodofunctionalization of Unsaturated Systems
- Barluenga, J. 1
- Rodríguez, M.A. 1
- Campos, P.J. 1
- Asensio, G. 2
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1
Universidad de Oviedo
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2
Universitat de València
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ISSN: 0022-4936
Argitalpen urtea: 1987
Alea: 19
Orrialdeak: 1491-1492
Mota: Artikulua
beta Ver similares en nube de resultadosBeste argitalpen batzuk: Journal of the Chemical Society - Series Chemical Communications
Laburpena
A mixture of iodine and CuO·HBF4 reacts stereospecifically with olefins in the presence of a wide variety of nucleophiles (NaNO2, NaSO2Ar, Nal, Et3SiH, MeOPh and H2O) to give the corresponding 2-functionalized iodo compounds; the same reagents also cause iodofunctionalization of 1,3-dienes and acetylenes.