A General and Useful Copper(Ii)-promoted Iodofunctionalization of Unsaturated Systems

  1. Barluenga, J. 1
  2. Rodríguez, M.A. 1
  3. Campos, P.J. 1
  4. Asensio, G. 2
  1. 1 Universidad de Oviedo
    info

    Universidad de Oviedo

    Oviedo, España

    ROR https://ror.org/006gksa02

  2. 2 Universitat de València
    info

    Universitat de València

    Valencia, España

    ROR https://ror.org/043nxc105

Revista:
Journal of the Chemical Society - Series Chemical Communications

ISSN: 0022-4936

Any de publicació: 1987

Volum: 19

Pàgines: 1491-1492

Tipus: Article

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DOI: 10.1039/C39870001491 SCOPUS: 2-s2.0-37049070983 GOOGLE SCHOLAR

Altres publicacions en: Journal of the Chemical Society - Series Chemical Communications

Resum

A mixture of iodine and CuO·HBF4 reacts stereospecifically with olefins in the presence of a wide variety of nucleophiles (NaNO2, NaSO2Ar, Nal, Et3SiH, MeOPh and H2O) to give the corresponding 2-functionalized iodo compounds; the same reagents also cause iodofunctionalization of 1,3-dienes and acetylenes.