Formation of a dithiophosphinate rhodium(III) complex from the unstable three-membered ring species [(η5-C5Me5)(η1-PSPh2)RhPh2PS]. Crystal structure of [(η5-C5Me5)(η1-PSPh2)RhPh2SPS]

  1. Pinillos, M.T. 1
  2. Jarauta, M.P. 1
  3. Carmona, D. 1
  4. Oro, L.A. 1
  5. Apreda, M.C. 2
  6. Foces-Foces, C. 2
  7. Cano, F.H. 2
  1. 1 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  2. 2 Instituto de Química Física Rocasolano
    info

    Instituto de Química Física Rocasolano

    Madrid, España

    ROR https://ror.org/03xk60j79

Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Año de publicación: 1988

Volumen: 345

Número: 1-2

Páginas: C13-C16

Tipo: Artículo

SCOPUS: 2-s2.0-0002454575 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Organometallic Chemistry

Resumen

The complex [(η5-C5Me5)(η1-PSPh2)RhPh2PS] )1) has been prepared. The highly reactive three-membered ring rh-Ph2PS in 1 undergoes sulphur insertion to give the derivative [(η5-C5Me5)(η1-PSPh2)RhPh2SPS]] (2) containing the stable four-membered RhPh2SPS ring. The structure of complex 2 has been determined by X-ray crystallography. © 1988.