Formation of a dithiophosphinate rhodium(III) complex from the unstable three-membered ring species [(η5-C5Me5)(η1-PSPh2)RhPh2PS]. Crystal structure of [(η5-C5Me5)(η1-PSPh2)RhPh2SPS]
- Pinillos, M.T. 1
- Jarauta, M.P. 1
- Carmona, D. 1
- Oro, L.A. 1
- Apreda, M.C. 2
- Foces-Foces, C. 2
- Cano, F.H. 2
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1
Instituto de Nanociencia y Materiales de Aragón
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2
Instituto de Química Física Rocasolano
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ISSN: 0022-328X
Year of publication: 1988
Volume: 345
Issue: 1-2
Pages: C13-C16
Type: Article
beta Ver similares en nube de resultadosMore publications in: Journal of Organometallic Chemistry
Abstract
The complex [(η5-C5Me5)(η1-PSPh2)RhPh2PS] )1) has been prepared. The highly reactive three-membered ring rh-Ph2PS in 1 undergoes sulphur insertion to give the derivative [(η5-C5Me5)(η1-PSPh2)RhPh2SPS]] (2) containing the stable four-membered RhPh2SPS ring. The structure of complex 2 has been determined by X-ray crystallography. © 1988.