Formation and characterization of a benzoquinolate triplatinum cluster containing a μ3-PPh2 bridging system and two Pt-Pt bonds
- Díez, A. 1
- Forniés, J. 2
- García, A. 1
- Lalinde, E. 1
- Moreno, M.T. 1
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1
Universidad de La Rioja
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2
Universidad de Zaragoza
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ISSN: 1387-7003
Año de publicación: 2006
Volumen: 9
Número: 3
Páginas: 255-258
Tipo: Artículo
beta Ver similares en nube de resultadosOtras publicaciones en: Inorganic Chemistry Communications
Resumen
The reaction between [Pt(bzq)(μ-PPh2)]2 and cis-[Pt(C6F5)2(thf)2] (1:2 molar ratio) results in the formation of a bent benzoquinolate triplatinum cluster [Pt3(bzq)(μ-PPh2)2(C6F 5)3] 1, which has been characterized by X-ray crystallography. The structure shows the presence of μ2-PPh 2 and [μ3-PPh(1,2-η2-Ph)- κ3P] bridging ligands and two platinum-platinum bonds. © 2005 Elsevier B.V. All rights reserved.