Polygold (1-adamantyl)ammoniun Salts

  1. López-de-Luzuriaga, J.M. 12
  2. Schier, A. 1
  3. Schmidbaur, H. 1
  1. 1 Technical University Munich
    info

    Technical University Munich

    Múnich, Alemania

    ROR https://ror.org/02kkvpp62

  2. 2 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Chemische Berichte

ISSN: 0009-2940

Año de publicación: 1997

Volumen: 130

Número: 2

Páginas: 221-223

Tipo: Artículo

DOI: 10.1002/CBER.19971300213 SCOPUS: 2-s2.0-0345672336 WoS: WOS:A1997WK02100011 GOOGLE SCHOLAR

Otras publicaciones en: Chemische Berichte

Repositorio institucional: lock_openAcceso abierto Editor

Resumen

The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C10H15N[Au(PPh3)]3) +BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C10H15N[Au(PPh3)]4) 2+{BF4-)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination. © VCH Verlagsgesellschaft mbH.