Polygold (1-adamantyl)ammoniun Salts
- López-de-Luzuriaga, J.M. 12
- Schier, A. 1
- Schmidbaur, H. 1
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1
Technical University Munich
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2
Universidad de La Rioja
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ISSN: 0009-2940
Ano de publicación: 1997
Volume: 130
Número: 2
Páxinas: 221-223
Tipo: Artigo
Outras publicacións en: Chemische Berichte
Resumo
The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C10H15N[Au(PPh3)]3) +BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C10H15N[Au(PPh3)]4) 2+{BF4-)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination. © VCH Verlagsgesellschaft mbH.