Experimental and theoretical evidence of the first Au(I)...Bi(III) interaction

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. López-De-Luzuriaga, J.M. 1
  4. Monge, M. 1
  5. Nema, M. 1
  6. Olmos, M.E. 1
  7. Pérez, J. 1
  8. Silvestru, C. 3
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Babeș-Bolyai University
    info

    Babeș-Bolyai University

    Cluj, Rumanía

    ROR https://ror.org/02rmd1t30

Zeitschrift:
Chemical Communications

ISSN: 1359-7345

Datum der Publikation: 2007

Ausgabe: 6

Seiten: 571-573

Art: Artikel

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DOI: 10.1039/B613365G SCOPUS: 2-s2.0-33846781121 WoS: WOS:000243841200006 GOOGLE SCHOLAR

Andere Publikationen in: Chemical Communications

Zusammenfassung

Complex [Au(C6F5)2][Bi(C6H 4CH2NMe2-2)2] 1 displays the first example of an interaction between Au(i) and Bi(iii), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%). © The Royal Society of Chemistry.