Experimental and theoretical evidence of the first Au(I)...Bi(III) interaction
- Fernández, E.J. 1
- Laguna, A. 2
- López-De-Luzuriaga, J.M. 1
- Monge, M. 1
- Nema, M. 1
- Olmos, M.E. 1
- Pérez, J. 1
- Silvestru, C. 3
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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3
Babeș-Bolyai University
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ISSN: 1359-7345
Any de publicació: 2007
Volum: 6
Pàgines: 571-573
Tipus: Article
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Resum
Complex [Au(C6F5)2][Bi(C6H 4CH2NMe2-2)2] 1 displays the first example of an interaction between Au(i) and Bi(iii), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%). © The Royal Society of Chemistry.