Metal-induced phosphorescence in (Pentafluorophenyl)gold(III) complexes

  1. Bojan, V.R. 1
  2. López-De-Luzuriaga, J.M. 1
  3. Manso, E. 1
  4. Monge, M. 1
  5. Olmos, M.E. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Journal:
Organometallics

ISSN: 0276-7333

Year of publication: 2011

Volume: 30

Issue: 17

Pages: 4486-4489

Type: Article

DOI: 10.1021/OM200537W SCOPUS: 2-s2.0-80052432772 WoS: WOS:000294647500005 GOOGLE SCHOLAR

More publications in: Organometallics

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Cited by

  • Scopus Cited by: 13 (12-01-2023)
  • Web of Science Cited by: 12 (31-12-2022)

JCR (Journal Impact Factor)

  • Year 2011
  • Journal Impact Factor: 3.963
  • Journal Impact Factor without self cites: 3.118
  • Article influence score: 0.831
  • Best Quartile: Q1
  • Area: CHEMISTRY, INORGANIC & NUCLEAR Quartile: Q1 Rank in area: 6/44 (Ranking edition: SCIE)
  • Area: CHEMISTRY, ORGANIC Quartile: Q1 Rank in area: 10/56 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2011
  • SJR Journal Impact: 2.0
  • Best Quartile: Q1
  • Area: Inorganic Chemistry Quartile: Q1 Rank in area: 7/69
  • Area: Organic Chemistry Quartile: Q1 Rank in area: 19/181
  • Area: Physical and Theoretical Chemistry Quartile: Q1 Rank in area: 19/167

Scopus CiteScore

  • Year 2011
  • CiteScore of the Journal : 6.9
  • Area: Inorganic Chemistry Percentile: 92
  • Area: Organic Chemistry Percentile: 89
  • Area: Physical and Theoretical Chemistry Percentile: 89

Abstract

The complexes [Au(C6F5)2(4-X-Py) 2]ClO4 (X = CN (1), H (2), CH3 (3)) and [Au(C6F5)Cl2(4-X-Py)] (X = CN (4), H (5), CH3 (6)) have been synthesized. The crystal structure of complexes 1, 3•0.5Et2O, 4, and 5 have been determined by X-ray diffraction methods. The photophysical behavior of all complexes has been studied experimentally through UV/vis spectroscopy and photoluminescence studies. TD-DFT calculations and full optimization of the ground state (S0) and lowest triplet excited state (T1) have been carried out in order to assign the photophysical properties of the complexes. © 2011 American Chemical Society.