Metal-induced phosphorescence in (Pentafluorophenyl)gold(III) complexes

  1. Bojan, V.R. 1
  2. López-De-Luzuriaga, J.M. 1
  3. Manso, E. 1
  4. Monge, M. 1
  5. Olmos, M.E. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Organometallics

ISSN: 0276-7333

Año de publicación: 2011

Volumen: 30

Número: 17

Páginas: 4486-4489

Tipo: Artículo

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DOI: 10.1021/OM200537W SCOPUS: 2-s2.0-80052432772 WoS: WOS:000294647500005 GOOGLE SCHOLAR

Otras publicaciones en: Organometallics

Resumen

The complexes [Au(C6F5)2(4-X-Py) 2]ClO4 (X = CN (1), H (2), CH3 (3)) and [Au(C6F5)Cl2(4-X-Py)] (X = CN (4), H (5), CH3 (6)) have been synthesized. The crystal structure of complexes 1, 3•0.5Et2O, 4, and 5 have been determined by X-ray diffraction methods. The photophysical behavior of all complexes has been studied experimentally through UV/vis spectroscopy and photoluminescence studies. TD-DFT calculations and full optimization of the ground state (S0) and lowest triplet excited state (T1) have been carried out in order to assign the photophysical properties of the complexes. © 2011 American Chemical Society.