Metal-induced phosphorescence in (Pentafluorophenyl)gold(III) complexes
- Bojan, V.R. 1
- López-De-Luzuriaga, J.M. 1
- Manso, E. 1
- Monge, M. 1
- Olmos, M.E. 1
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1
Universidad de La Rioja
info
ISSN: 0276-7333
Year of publication: 2011
Volume: 30
Issue: 17
Pages: 4486-4489
Type: Article
beta Ver similares en nube de resultadosMore publications in: Organometallics
Abstract
The complexes [Au(C6F5)2(4-X-Py) 2]ClO4 (X = CN (1), H (2), CH3 (3)) and [Au(C6F5)Cl2(4-X-Py)] (X = CN (4), H (5), CH3 (6)) have been synthesized. The crystal structure of complexes 1, 3•0.5Et2O, 4, and 5 have been determined by X-ray diffraction methods. The photophysical behavior of all complexes has been studied experimentally through UV/vis spectroscopy and photoluminescence studies. TD-DFT calculations and full optimization of the ground state (S0) and lowest triplet excited state (T1) have been carried out in order to assign the photophysical properties of the complexes. © 2011 American Chemical Society.