[Au2Tl2(C6Cl5)4]·(CH3)2C=O: A Luminescent Loosely Bound Butterfly Cluster with a Tl(I)-Tl(I) Interaction
- Fernández, E.J. 1
- López-De-Luzuriaga, J.M. 1
- Monge, M. 1
- Olmos, M.E. 1
- Pérez, J. 1
- Laguna, A. 2
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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ISSN: 0002-7863
Year of publication: 2002
Volume: 124
Issue: 21
Pages: 5942-5943
Type: Article
beta Ver similares en nube de resultadosMore publications in: Journal of the American Chemical Society
Abstract
By reaction of NBu4[Au(C6Cl5)2] with TlPF6 in acetone the complex [Au2Tl2(C6Cl5)4]·(CH3)2C=O is obtained, which shows a butterfly type arrangement of metals through short Au(I)-Tl(I) and Tl(I)-Tl(I) interactions. The last one is likely to be responsible for its luminescence behavior. Copyright © 2002 American Chemical Society.