Study of the Nature of Closed-Shell HgII⋯MI (M = Cu, Ag, Au) Interactions

  1. López-De-Luzuriaga, J.M. 1
  2. Monge, M. 1
  3. Olmos, M.E. 1
  4. Pascual, D. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    GRID grid.119021.a

Journal:
Organometallics

ISSN: 0276-7333

Year of publication: 2015

Volume: 34

Issue: 12

Pages: 3029-3038

Type: Article

Export: RIS
DOI: 10.1021/acs.organomet.5b00334 SCOPUS: 2-s2.0-84934955934 WoS: 000356903100038 GOOGLE SCHOLAR

Metrics

Cited by

  • Scopus Cited by: 20 (14-07-2021)

Journal Citation Reports

  • Year 2015
  • Journal Impact Factor: 4.186
  • Best Quartile: Q1
  • Area: CHEMISTRY, INORGANIC & NUCLEAR Quartile: Q1 Rank in area: 9/46 (Ranking edition: SCIE)
  • Area: CHEMISTRY, ORGANIC Quartile: Q1 Rank in area: 12/59 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2015
  • SJR Journal Impact: 1.923
  • Best Quartile: Q1
  • Area: Inorganic Chemistry Quartile: Q1 Rank in area: 5/73
  • Area: Organic Chemistry Quartile: Q1 Rank in area: 16/188
  • Area: Physical and Theoretical Chemistry Quartile: Q1 Rank in area: 16/165

CiteScore

  • Year 2015
  • CiteScore of the Journal : 7.9
  • Area: Inorganic Chemistry Percentile: 94
  • Area: Organic Chemistry Percentile: 92
  • Area: Physical and Theoretical Chemistry Percentile: 88

Abstract

Heteronuclear complexes [HgM(o-C<inf>6</inf>H<inf>4</inf>PPh<inf>2</inf>)<inf>2</inf>]X (M = Au, X = ClO<inf>4</inf> (1); M = Ag, X = BF<inf>4</inf> (2); M = Ag, X = CF<inf>3</inf>CO<inf>2</inf> (3); M = Cu, X = Br (4)) were prepared by the treatment of [Hg(o-C<inf>6</inf>H<inf>4</inf>PPh<inf>2</inf>)<inf>2</inf>] with one equivalent of the corresponding coinage metal salt. Their crystal structures, determined by X-ray diffraction methods, display HgII⋯MI (M = Au, Ag, Cu) contacts. Ab initio calculations show similar interaction energies (ca.40 kJ·mol-1) and similar origin (dispersive forces) for these Hg⋯Au, Hg⋯Ag, and Hg⋯Cu interactions. (Chemical Presented). © 2015 American Chemical Society.