Study of the Nature of Closed-Shell HgII⋯MI (M = Cu, Ag, Au) Interactions

  1. López-De-Luzuriaga, J.M. 1
  2. Monge, M. 1
  3. Olmos, M.E. 1
  4. Pascual, D. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Journal:
Organometallics

ISSN: 0276-7333

Year of publication: 2015

Volume: 34

Issue: 12

Pages: 3029-3038

Type: Article

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DOI: 10.1021/ACS.ORGANOMET.5B00334 SCOPUS: 2-s2.0-84934955934 WoS: WOS:000356903100038 GOOGLE SCHOLAR

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Abstract

Heteronuclear complexes [HgM(o-C<inf>6</inf>H<inf>4</inf>PPh<inf>2</inf>)<inf>2</inf>]X (M = Au, X = ClO<inf>4</inf> (1); M = Ag, X = BF<inf>4</inf> (2); M = Ag, X = CF<inf>3</inf>CO<inf>2</inf> (3); M = Cu, X = Br (4)) were prepared by the treatment of [Hg(o-C<inf>6</inf>H<inf>4</inf>PPh<inf>2</inf>)<inf>2</inf>] with one equivalent of the corresponding coinage metal salt. Their crystal structures, determined by X-ray diffraction methods, display HgII⋯MI (M = Au, Ag, Cu) contacts. Ab initio calculations show similar interaction energies (ca.40 kJ·mol-1) and similar origin (dispersive forces) for these Hg⋯Au, Hg⋯Ag, and Hg⋯Cu interactions. (Chemical Presented). © 2015 American Chemical Society.