A highly efficient, green and recoverable catalytic system for the epoxidation of fatty esters and biodiesel with H 2O 2

  1. De Torres, M. 1
  2. Arends, I.W.C.E. 4
  3. Mayoral, J.A. 3
  4. Pires, E. 1
  5. Jiménez-Osés, G. 12
  1. 1 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  2. 2 University of California Los Angeles
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    University of California Los Angeles

    Los Ángeles, Estados Unidos

    ROR https://ror.org/046rm7j60

  3. 3 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  4. 4 Delft University of Technology
    info

    Delft University of Technology

    Delft, Holanda

    ROR https://ror.org/02e2c7k09

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Revista:
Applied Catalysis A: General

ISSN: 0926-860X

Año de publicación: 2012

Volumen: 425-426

Páginas: 91-96

Tipo: Artículo

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DOI: 10.1016/J.APCATA.2012.03.009 SCOPUS: 2-s2.0-84859918466 WoS: WOS:000303905900012 GOOGLE SCHOLAR

Otras publicaciones en: Applied Catalysis A: General

Resumen

A highly efficient and green strategy for the epoxidation of fatty esters, combining a green oxidant (aqueous hydrogen peroxide) and a recyclable catalyst (a seleninic acid derivative) is presented. The possibility of integrating renewable solvents derived from glycerol in the productive cycle of biodiesel commodities is also explored. Fluorinated solvents (both commercial and glycerol-derived) play a double key role on this methodology: on the one hand, they strongly accelerate epoxidation reaction with respect to common non-fluorinated solvents and, on the other hand, some of them allow catalyst recycling. Mono- and polyunsaturated fatty esters, as well as soy biodiesel have been epoxidized with excellent yields and selectivities towards epoxide under the optimal conditions and with minimum catalyst loads. © 2012 Elsevier B.V.