Hydantoin-based molecular photoswitches

  1. Martínez-López, D. 1
  2. Yu, M.-L. 3
  3. García-Iriepa, C. 1
  4. Campos, P.J. 1
  5. Frutos, L.M. 2
  6. Golen, J.A. 3
  7. Rasapalli, S. 3
  8. Sampedro, D. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Universidad de Alcalá
    info

    Universidad de Alcalá

    Alcalá de Henares, España

    ROR https://ror.org/04pmn0e78

  3. 3 University of Massachusetts Dartmouth
    info

    University of Massachusetts Dartmouth

    New Bedford, Estados Unidos

    ROR https://ror.org/00fzmm222

Revue:
Journal of Organic Chemistry

ISSN: 0022-3263

Année de publication: 2015

Volumen: 80

Número: 8

Pages: 3929-3939

Type: Article

DOI: 10.1021/ACS.JOC.5B00244 SCOPUS: 2-s2.0-84928139929 WoS: WOS:000353315000022 GOOGLE SCHOLAR

D'autres publications dans: Journal of Organic Chemistry

Indicateurs

Cité par

  • Scopus Cité par: 32 (12-11-2023)
  • 'Web of Science' Cité par: 35 (10-10-2023)
  • Dimensions Cité par: 30 (30-03-2023)

JCR (Journal Impact Factor)

  • Año 2015
  • Factor de impacto de la revista: 4.785
  • Factor de impacto sin autocitas: 4.283
  • Article influence score: 1.051
  • Cuartil mayor: Q1
  • Área: CHEMISTRY, ORGANIC Cuartil: Q1 Posición en el área: 7/59 (Edicion: SCIE)

SCImago Journal Rank

  • Año 2015
  • Impacto SJR de la revista: 1.997
  • Cuartil mayor: Q1
  • Área: Organic Chemistry Cuartil: Q1 Posición en el área: 15/189

Scopus CiteScore

  • Año 2015
  • CiteScore de la revista: 8.1
  • Área: Organic Chemistry Percentil: 93
  • Área: Medicine (all) Percentil: 88

Dimensions

(Datos actualizados a fecha de 30-03-2023)
  • Citas totales: 30
  • Citas recientes: 11
  • Relative Citation Ratio (RCR): 0.96
  • Field Citation Ratio (FCR): 4.98

Résumé

A new family of molecular photoswitches based on arylidenehydantoins is described together with their synthesis and photochemical and photophysical studies. A series of hydantoin derivatives have been prepared as single isomers using simple and versatile chemistry in good yields. Our studies show that the photostationary states of these compounds can be easily controlled by means of external factors, such as the light source or filters. Moreover, the detailed investigations proved that these switches are efficient (i.e., they make efficient use of the light energy, are high fatigue resistant, and are very photostable). In some cases, the switches can be completely turned on/off, a desirable feature for specific applications. A series of theoretical calculations have also been carried out to understand the photoisomerization mechanism at the molecular level. © 2015 American Chemical Society.