Co-ordinative ability of the new compounds [Ti(eta5-C5H4R)2(CºCBut)2] (R= PPh2, Ph2P=O, Ph2P=S) as precursors in the synthesis of heterodi- and heterotri-nuclear species. Crystal structure of [CuCl(µ-eta5:kappaP-C5H4PPh2)2Ti(µ-eta2-CºCBut)2CuCl]

  1. Delgado, E. 3
  2. Hernández, E. 3
  3. Mansilla, N. 3
  4. Teresa Moreno, M. 1
  5. Sabat, M. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 University of Virginia
    info

    University of Virginia

    Charlottesville, Estados Unidos

    ROR https://ror.org/0153tk833

  3. 3 Universidad Autónoma de Madrid
    info

    Universidad Autónoma de Madrid

    Madrid, España

    ROR https://ror.org/01cby8j38

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Revista:
Journal of the Chemical Society-Dalton Transactions

ISSN: 0300-9246

Año de publicación: 1999

Volumen: 4

Páginas: 533-538

Tipo: Artículo

DOI: 10.1039/A807905F SCOPUS: 2-s2.0-37549058464 WoS: WOS:000079052300006 GOOGLE SCHOLAR

Otras publicaciones en: Journal of the Chemical Society-Dalton Transactions

Resumen

full title:Co-ordinative ability of the new compounds [Ti(η5-C5H4R)2-(C≡CBu t)2] (R = PPh2, Ph2P=O or Ph2P=S) as precursors in the synthesis of heterodi- And heterotri-nuclear species. Crystal structure of [ClCu(μ-η5 : κP-C5H4PPh2) 2Ti(μ-η2-C≡CBut)2CuCl] New mononuclear bis(alkyne) derivatives of functionalised titanocene [Ti(η5-C5H4R)2(C≡CBu t)2] (R = PPh2 1, Ph2P=O 7 or Ph2P=S 8) have been isolated by reaction of [Ti(η5-C5H4R)2Cl2] (R = PPh2, Ph2P=O or Ph2P=S) and LiC≡CBut in diethyl ether. The reactions of the former species with (CuCl)n and [Mo(CO)4(nbd)] have been investigated. Novel heterobi- [LnM(μ-η5 : κP-C5H4PPh2) 2Ti(̊-η2-C≡CBut)2] [MLn = CuCl 4 or Mo(CO)4 5], [{η5-C5H4P(E)Ph2} 2Ti(μ-η2-C≡CBut)2CuCl] (E = O 9 or S 10) and heterotri-nuclear complexes [LnM(μ-η5 : κP-C5H4PPh2) 2Ti(μ-η2-C≡CBut)2CuCl] [MLn= CuCl 2 or Mo(CO)4 6] have been synthesized. The crystal structure of compound 2 has been solved.