Chiral hydrogen bond environment providing unidirectional rotation in photoactive molecular motors
- García-Iriepa, C. 12
- Marazzi, M. 2
- Zapata, F. 2
- Valentini, A. 2
- Sampedro, D. 1
- Frutos, L.M. 2
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1
Universidad de La Rioja
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2
Universidad de Alcalá
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ISSN: 1948-7185
Year of publication: 2013
Volume: 4
Issue: 9
Pages: 1389-1396
Type: Article
More publications in: Journal of Physical Chemistry Letters
Metrics
JCR (Journal Impact Factor)
- Year 2013
- Journal Impact Factor: 6.687
- Journal Impact Factor without self cites: 6.228
- Article influence score: 2.257
- Best Quartile: Q1
- Area: CHEMISTRY, PHYSICAL Quartile: Q1 Rank in area: 19/136 (Ranking edition: SCIE)
- Area: MATERIALS SCIENCE, MULTIDISCIPLINARY Quartile: Q1 Rank in area: 21/251 (Ranking edition: SCIE)
- Area: NANOSCIENCE & NANOTECHNOLOGY Quartile: Q1 Rank in area: 13/73 (Ranking edition: SCIE)
- Area: PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Quartile: Q1 Rank in area: 2/33 (Ranking edition: SCIE)
SCImago Journal Rank
- Year 2013
- SJR Journal Impact: 3.529
- Best Quartile: Q1
- Area: Physical and Theoretical Chemistry Quartile: - Rank in area: 6/172
- Area: Nanoscience and Nanotechnology Quartile: Q1 Rank in area: 9/93
- Area: Materials Science (miscellaneous) Quartile: Q1 Rank in area: 20/617
Scopus CiteScore
- Year 2013
- CiteScore of the Journal : 11.4
- Area: Materials Science (all) Percentile: 96
- Area: Medicine (all) Percentile: 94
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Abstract
Generation of a chiral hydrogen bond environment in efficient molecular photoswitches is proposed as a novel strategy for the design of photoactive molecular motors. Here, the following strategy is used to design a retinal-based motor presenting singular properties: (i) a single excitation wavelength is needed to complete the unidirectional rotation process (360); (ii) the absence of any thermal step permits the process to take place at low temperatures; and (iii) the ultrafast process permits high rotational frequencies. © 2013 American Chemical Society.